Diazaborines oxidize slowly with H<sub>2</sub>O<sub>2</sub> but rapidly with peroxynitrite in aqueous buffer
Jack G. Haggett, Gun Su Han, Angela R. Moser, Julian V. A. Golzwarden, Shubham Vyas, Dylan W. Domaille
Abstract
Diazaborines react slowly with H 2 O 2 but rapidly with ONOO − , offering a new platform for discriminating between these two cellular ROS.
Topics & Concepts
PeroxynitriteChemistryHydrogen peroxideReactive oxygen speciesAqueous solutionYield (engineering)OxygenRadicalPhotochemistryPeroxideMoleculeReactive intermediateOrganic chemistryCatalysisSuperoxideBiochemistryEnzymeMaterials scienceMetallurgyLuminescence and Fluorescent MaterialsMolecular Sensors and Ion DetectionOrganoboron and organosilicon chemistry