Tandem-like vanadium cluster chains in a polyoxovanadate-based metal–organic framework for efficient catalytic oxidation of sulfides
Tian‐Yi Dang, Run‐Han Li, Hong‐Rui Tian, Qian Wang, Ying Lü, Shuxia Liu
Abstract
The vanadium cluster chain in V-Ni-MOF can efficiently catalyze the oxidation of sulfides with hydrogen peroxide as the oxidant, achieving the complete conversion from sulfides to sulfones within 1 hour at 40 °C.
Topics & Concepts
VanadiumTandemCatalysisHydrogen peroxideCluster (spacecraft)ChemistryMetalInorganic chemistryMaterials scienceOrganic chemistryComputer scienceProgramming languageComposite materialPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions