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Spatial enantioseparation of gaseous chiral molecules

Бо Лю, Chong Ye, C. P. Sun, Yong Li

2021Physical review. A/Physical review, A22 citationsDOIOpen Access PDF

Abstract

We explore the spatial enantioseparation of gaseous chiral molecules for the cyclic three-level systems coupled with three electromagnetic fields. Due to molecular rotations, the specific requirements of the polarization directions of the three electromagnetic fields lead to the space-dependent part of the overall phase of the coupling strengths. Thus, the overall phase of the coupling strengths, which differs with $\ensuremath{\pi}$ for the enantiomers in the cyclic three-level model of chiral molecules, varies intensely in the length scale of the typical wavelength of the applied electromagnetic fields. Under the induced gauge potentials resulting from the space-dependent part of the overall phase and the space-dependent intensities of coupling strengths, we further show spatial enantioseparation for typical parameters of gaseous chiral molecules.

Topics & Concepts

Coupling (piping)EnantiomerMoleculeElectromagnetic fieldPolarization (electrochemistry)Space (punctuation)Spatial configurationPhase (matter)Chemical physicsGauge (firearms)PhysicsMolecular physicsMaterials scienceChemistryQuantum mechanicsOrganic chemistryPhysical chemistryLinguisticsMetallurgyDistribution (mathematics)PhilosophyMathematical analysisMathematicsCold Atom Physics and Bose-Einstein CondensatesMolecular spectroscopy and chiralitySpectroscopy and Quantum Chemical Studies
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