Guest-tuned proton conductivity of a porphyrinylphosphonate-based hydrogen-bonded organic framework
Yijie Wang, Jianbo Yin, Di Liu, Chengqi Gao, Zixi Kang, Rongming Wang, Daofeng Sun, Jianzhuang Jiang
Abstract
A porous porphyrin-based hydrogen-bonded organic framework (HOF) was constructed, and its proton conductivity was improved through a two-step guest-tuned strategy. After regulation, the proton conductivity of the HOF reaches 1.59 × 10<sup>−1</sup> S cm<sup>−1</sup> at 80 °C and 99% RH.
Topics & Concepts
ConductivityProtonPorphyrinHydrogenMaterials sciencePorosityAnalytical Chemistry (journal)Inorganic chemistryChemistryPhysical chemistryPhotochemistryPhysicsOrganic chemistryComposite materialNuclear physicsMetal-Organic Frameworks: Synthesis and ApplicationsFuel Cells and Related MaterialsCovalent Organic Framework Applications