Melting point of dried gold nanoparticles prepared with ultrasonic spray pyrolysis and lyophilisation
Žiga Jelen, Marcin Krajewski, Franc Zupanič, Peter Majerič, Tilen Švarc, Ivan Anžel, Jernej Ekar, Sz‐Chian Liou, Jerzy Kubacki, Mateusz Tokarczyk, Rebeka Rudolf
Abstract
Abstract A coupled process of ultrasonic spray pyrolysis and lyophilisation was used for the synthesis of dried gold nanoparticles. Two methods were applied for determining their melting temperature: uniaxial microcompression and differential scanning calorimetry (DSC) analysis. Uniaxial microcompression resulted in sintering of the dried gold nanoparticles at room temperature with an activation energy of 26–32.5 J/g, which made it impossible to evaluate their melting point. Using DSC, the melting point of the dried gold nanoparticles was measured to be around 1064.3°C, which is close to pure gold. The reason for the absence of a melting point depression in dried gold nanoparticles was their exothermic sintering between 712 and 908.1°C.