Photocatalytic synthesis of 10-phenanthrenols<i>via</i>intramolecular cycloaromatization under oxidant-free conditions
Junli Li, Xiaoying Niu, Yifan Song, Jian‐Long Du, Shigang Shen, Xiu‐Long Yang
Abstract
A novel tandem photocycloaddition/dehydrogenative aromatization with hydrogen evolution of ortho biaryl-appended 1,3-dicarbonyl compounds for the synthesis of 10-phenanthrenol via cobaloxime catalysis is disclosed.
Topics & Concepts
ChemistryIntramolecular forcePhotocatalysisCombinatorial chemistryMedicinal chemistryOrganic chemistryCatalysisRadical Photochemical ReactionsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry