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Metal–Organic Framework Derived Bimetallic Materials for Electrochemical Energy Storage

Soheila Sanati, Reza Abazari, Josep Albero, Ali Morsali, Hermenegildo Garcı́a, Zibin Liang, Ruqiang Zou

2020Angewandte Chemie International Edition347 citationsDOIOpen Access PDF

Abstract

Supercapacitors (SCs), showing excellent power density, long service life, and high reversibility, have received great attention because of the increasing demand for energy storage devices. To further improve their performance, it is essential to develop advanced electrode materials. One group of materials, porous crystalline solids referred to as metal-organic frameworks (MOFs), have proved to be excellent templates for synthesizing functional materials to be employed in the preparation of electrodes for SCs. In comparison to monometallic MOFs, bimetallic MOFs and their derivatives offer a number of advantages, including tunable electrochemical activity, high charge capacity, and improved electrical conductivity. This review focuses on the use of MOF-derived bimetallic materials in SCs, the origin of the improved performance, and the latest developments in the field. Furthermore, the challenges and perspectives in this research area are discussed.

Topics & Concepts

Bimetallic stripElectrochemical energy storageElectrochemistryEnergy storageElectrochemical energy conversionMaterials scienceMetal-organic frameworkMetalMetallurgyChemistrySupercapacitorElectrodeOrganic chemistryPhysicsThermodynamicsPower (physics)Physical chemistryAdsorptionSupercapacitor Materials and FabricationAdvancements in Battery MaterialsAdvanced Battery Materials and Technologies