Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers
Yu Gong, Wang‐Kang Han, Hui‐Shu Lu, Qing‐Tao Hu, Huan Tu, Pei-Ni Li, Xiaodong Yan, Zhi‐Guo Gu
Abstract
New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.
Topics & Concepts
Materials scienceSpin crossoverLigand (biochemistry)Single crystalCrystallographyCoordination polymerMetal-organic frameworkCrystal (programming language)Transition metalSpin transitionSpin (aerodynamics)Transformation (genetics)PolymerCondensed matter physicsChemical physicsChemistryComposite materialThermodynamicsOrganic chemistryComputer scienceCatalysisGeneBiochemistryPhysicsProgramming languageReceptorAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes