Effect of ligand substituents and tuning the spin-state switching in manganese(<scp>iii</scp>) complexes
Subrata Ghosh, Sukanya Bagchi, Sujit Kamilya, Abhishake Mondal
Abstract
surrounding offered by the flexible hexadentate ligand in a distorted octahedral geometry. Complex 1 remains in the high spin state over the entire temperature range, while complex 2 shows a reversible and complete two-step thermo-induced spin-state switching. An incomplete spin-state switching from a high spin to an intermediate high-spin low-spin (1 : 1) state was observed for complex 3. Single-crystal X-ray structural studies show the presence of three different spin states in 2 during the occurrence of the spin-state switching process. Electrochemical investigations showed that the reduced state of manganese(iii) centers in 3 is easily accessible in comparison to complexes 1 and 2.