Cobalt pincer-type complexes demonstrating unique selectivity for the hydroboration reaction of olefins under mild conditions
Dariusz Lewandowski, Grzegorz Hreczycho
Abstract
Pincer cobalt complexes based on a triazine backbone have been used as efficient catalysts for the hydroboration reaction of alkenes. The presented protocol shows unique selectivity distinguishing a vinylsilyl from another alkenyl or alkynyl groups.
Topics & Concepts
HydroborationSelectivityChemistryPincer movementCobaltCatalysisOrganic chemistryCombinatorial chemistryMedicinal chemistryOrganoboron and organosilicon chemistryChemical Synthesis and AnalysisCatalytic Cross-Coupling Reactions