Self-poled piezoelectric polymer composites via melt-state energy implantation
Zhao‐Xia Huang, Lanwei Li, Yunzhi Huang, Wen-Xu Rao, Haowei Jiang, Jin Wang, Huanhuan Zhang, Hezhi He, Jinping Qu
Abstract
Abstract Lightweight flexible piezoelectric polymers are demanded for various applications. However, the low instinctively piezoelectric coefficient ( i.e . d33) and complex poling process greatly resist their applications. Herein, we show that introducing dynamic pressure during fabrication is capable for poling polyvinylidene difluoride/barium titanate (PVDF/BTO) composites with d33 of ~51.20 pC/N at low density of ~0.64 g/cm 3 . The melt-state dynamic pressure driven energy implantation induces structure evolutions of both PVDF and BTO are demonstrated as reasons for self-poling. Then, the porous material is employed as pressure sensor with a high output of ~20.0 V and sensitivity of ~132.87 mV/kPa. Besides, the energy harvesting experiment suggests power density of ~58.7 mW/m 2 can be achieved for 10 N pressure with a long-term durability. In summary, we not only provide a high performance lightweight, flexible piezoelectric polymer composite towards sustainable self-powered sensing and energy harvesting, but also pave an avenue for electrical-free fabrication of piezoelectric polymers.