Efficient Energy-Transfer-Induced High Photoelectric Conversion in a Dye-Encapsulated Ionic Pyrene-Based Metal–Organic Framework
Jian‐Hua Qin, Wenjing Qin, Zhi Xiao, Jikun Yang, Huarui Wang, Xiao‐Gang Yang, Dong‐Sheng Li, Lu‐Fang Ma
Abstract
The relationship between the aggregation states of pyrene-based linkers and the photoluminescence/photoelectric performance was well studied by the formation of an anionic metal–organic framework, [BMI]2[Mg3(TBAPy)2(H2O)4]·2dioxane, which shows highly enhanced light-harvesting and photoelectric conversion efficiency by the encapsulation of D−π–A cation dyes.
Topics & Concepts
ChemistryPyrenePhotoelectric effectPhotochemistryIonic bondingPhotoluminescenceMetalEnergy transferEnergy transformationChemical engineeringInorganic chemistryIonOptoelectronicsChemical physicsOrganic chemistryPhysicsThermodynamicsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsNanoplatforms for cancer theranostics