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Li<sub>6.58</sub>Na<sub>7.43</sub>Sr<sub>4</sub>(B<sub>9</sub>O<sub>18</sub>)(B<sub>12</sub>O<sub>24</sub>)Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B<sub>9</sub>O<sub>18</sub> FBB

Feixiang Wang, Yun Yang, Congcong Jin, Shilie Pan

2022Inorganic Chemistry Frontiers18 citationsDOI

Abstract

A new borate exhibiting the unprecedented combination of the largest two highly polymerized B–O clusters with novel B 9 O 18 FBB was obtained. And the corresponding design strategies for borates with two polymerized B–O clusters are proposed.

Topics & Concepts

BoronPolymerizationCrystallographyMaterials scienceChemistryPolymerOrganic chemistryComposite materialCrystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography
Li<sub>6.58</sub>Na<sub>7.43</sub>Sr<sub>4</sub>(B<sub>9</sub>O<sub>18</sub>)(B<sub>12</sub>O<sub>24</sub>)Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B<sub>9</sub>O<sub>18</sub> FBB | Litcius