Elucidating the paramagnetic interactions of an inorganic–organic hybrid radical-functionalized Mn-Anderson cluster
Chang‐Gen Lin, Marie Hutin, Christoph Busche, Nicola L. Bell, De‐Liang Long, Leroy Cronin
Abstract
A family of six polyoxometalate-based magnetic compounds were synthesized by anchoring N-oxide type TEMPO radicals onto an Anderson type polyoxometalate cluster. The complexes were structurally characterised by single crystal X-ray diffraction and the intramolecular paramagnetic interactions between TEMPO radicals and Mn ions of the resulting hybrids were investigated in detail by electron paramagnetic resonance and the Evans NMR method.
Topics & Concepts
PolyoxometalateCluster (spacecraft)ParamagnetismRadicalChemistryHybrid materialCrystallographyInorganic chemistryMaterials scienceOrganic chemistryCatalysisPhysicsCondensed matter physicsComputer scienceProgramming languagePolyoxometalates: Synthesis and ApplicationsMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and Applications