Persilylation of ferrocene: the ultimate discipline in sterically overcrowded metal complexes
Susanne M. Rupf, Robin Sievers, Paulin S. Riemann, Marc Reimann, Martin Kaupp, Carlo Fasting, Moritz Malischewski
Abstract
We report the isolation, for the first time, of a persilylated metallocene, FeC 10 (SiMe 2 H) 10 , with an unusual purple colour.
Topics & Concepts
Steric effectsFerroceneMetalChemistryStereochemistryOrganic chemistryPhysical chemistryElectrodeElectrochemistryOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistry