Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks
Qiuxue Lai, Zhaoqin Chu, Xinyi Xiao, Dejun Dai, Ting Song, Tian‐Yi Luo, Wenlei Tang, Xuan Feng, Zhiyuan Zhang, Tao Li, Hai Xiao, Jing Su, Chong Liu
Abstract
nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 μm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform.
Topics & Concepts
BenzeneChelationMetal-organic frameworkMetalMaterials scienceCombinatorial chemistryChemical engineeringCrystallographyInorganic chemistryChemistryPhysical chemistryOrganic chemistryMetallurgyAdsorptionEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsAdvanced Condensed Matter Physics