Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions
Panjuan Tang, Stefano Paganelli, Francesco Carraro, Matı́as Blanco, Raffaele Riccò, Carla Marega, Denis Badocco, Paolo Pastore, Christian J. Doonan, Stefano Agnoli
Abstract
A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
Topics & Concepts
HydroformylationChemoselectivityCatalysisMaterials scienceAldehydeSelectivityStyreneLeaching (pedology)ManganeseMetalOrganic chemistryRhodiumChemistryMetallurgyCopolymerPolymerEnvironmental scienceComposite materialSoil scienceSoil waterMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesDendrimers and Hyperbranched Polymers