Photoredox/copper-catalyzed coupling of terminal alkynes with P(O)SH compounds leading to alkynyl phosphorothioates
Zhipeng Zheng, Jiali He, Qianru Ma, Yumeng Zhang, Yan Liu, Guo Tang, Yufen Zhao
Abstract
The first pathway for the formation of alkynyl phosphorothioates via a visible-light-induced cross-dehydrogenative coupling reaction is reported.
Topics & Concepts
CatalysisChemistryCopperTerminal (telecommunication)Coupling (piping)PhotochemistryMedicinal chemistryCombinatorial chemistryStereochemistryOrganic chemistryMaterials scienceComputer scienceMetallurgyTelecommunicationsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions