Can a heavy trinitromethyl group always result in a higher density?
Ning Ding, Qi Sun, Xudong Xu, Yaqiong Li, Chaofeng Zhao, Shenghua Li, Siping Pang
Abstract
). Mechanistic studies indicated that the reduced density was due to the significantly weaker H-bonding and π-π interactions of TN-116, which produced looser stacking compared to that of LLM-116.
Topics & Concepts
Group (periodic table)ChemistryMaterials scienceCrystallographyOrganic chemistryEnergetic Materials and CombustionCrystallography and molecular interactionsChemical Reaction Mechanisms