Highly selective Suzuki reaction catalysed by a molecular Pd–P-MOF catalyst under mild conditions: role of ligands and palladium speciation
Daniele Cartagenova, Stephan Bachmann, Kurt Püntener, Michelangelo Scalone, Mark A. Newton, Fabio A. Peixoto Esteves, Thomas Rohrbach, Patrik P. Zimmermann, Jeroen A. van Bokhoven, Marco Ranocchiari
Abstract
A phosphine-functionalized MOF was used to prepare molecularly-defined palladium catalysts, active for Suzuki coupling in mild conditions. Their selectivity was correlated with the nature of the catalytic active site via XAS and NMR.
Topics & Concepts
PalladiumCatalysisPhosphineChemistrySelectivitySuzuki reactionCombinatorial chemistryOrganic chemistryCatalytic Cross-Coupling ReactionsMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications