Bifunctional 1-Boc-3-Iodoazetidine Enhancing Lithium Anode Stability and Rechargeability of Lithium–Oxygen Batteries
Yanni Li, Fangling Jiang, Zhuang Sun, Osamu Yamamoto, Nobuyuki Imanishi, Tao Zhang
Abstract
Lithium anode protection is an effective strategy to prohibit the continuous loss of redox mediators (RMs) resulting from the unfavorable “shuttle effect” in lithium–oxygen batteries. In this work, an in situ Li anode protection method is designed by utilizing an organic compound, 1-Boc-3-iodoazetidine (BIA), as both a RM and an additive, to form a lithium anode protective layer. The reaction between Li metal and BIA can form lithium iodide (LiI) and lithium-based organometallic. LiI can effectively reduce the charging overpotential. Meanwhile, the in situ-formed anode protection layer (lithium-based organometallic) can not only effectively prevent RMs from being reduced by the lithium metal, but also inhibit the growth of lithium dendrites. As a result, the lithium–oxygen battery with BIA shows a long cycle life of 260 cycles with a notably reduced charging potential. In particular, the battery with BIA achieves an excellent lifespan of 160 cycles at a large current density of 2000 mA g–1.