Intermolecular oxyarylation of olefins with aryl halides and TEMPOH catalyzed by the phenolate anion under visible light
Kangjiang Liang, Qian Liu, Lei Shen, Xipan Li, Delian Wei, Liyan Zheng, Chengfeng Xia
Abstract
The phenolate anion was developed as a new photocatalyst with strong reduction potentials (−3.16 V <italic>vs.</italic> SCE) to reduction of aryl halides to aryl radicals through single electron transfer.
Topics & Concepts
ArylHalidePhotochemistryChemistryIntermolecular forceIonCatalysisRadicalElectron transferVisible spectrumInorganic chemistryMaterials scienceOrganic chemistryMoleculeAlkylOptoelectronicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques