Enhanced photo-Fenton catalysis <i>via</i> bandgap engineering of metalloporphyrin-based covalent organic framework shells on bimetallic metal–organic frameworks: accelerating Fe(<scp>iii</scp>)/Fe(<scp>ii</scp>) loop activation
Hui Wang, Xuefeng Zhang, Xiang‐Feng Wu, Yewei Kang, Yirui Huang, Zhao‐Ye Zhao, Ziyan Li, Tingting Zhou, Junchuan Wang, Wei Zhu, Chengsi Pan
Abstract
A metallized porphyrin-based COF shell was constructed on bimetal based NH 2 -Cu/Fe-MIL-101 nanoparticles, which demonstrates exceptional photo-Fenton catalytic efficiency and excellent stability.
Topics & Concepts
Bimetallic stripCatalysisMetal-organic frameworkCovalent bondChemistryMetalChemical engineeringPhotochemistryMaterials scienceOrganic chemistryEngineeringAdsorptionCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications