Rh-Catalyzed nitrene alkyne metathesis/formal C–N bond insertion cascade: synthesis of 3-iminoindolines
Kemiao Hong, Su Zhou, Wenhao Hu, Xinfang Xu
Abstract
A Rh-catalyzed nitrene/alkyne metathesis (NAM) cascade reaction terminated by a formal C–N bond insertion has been developed, which provides facile access to the tricyclic 3-iminoindolines in good yields with broad substrate scope.
Topics & Concepts
NitreneChemistryAlkyneCascadeMetathesisCatalysisSalt metathesis reactionSubstrate (aquarium)Combinatorial chemistryOrganic chemistryPolymerizationGeologyChromatographyOceanographyPolymerSynthetic Organic Chemistry MethodsSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods