Enhanced redox kinetics for hydrogen peroxide photosynthesis at high-concentration by encapsulating porphyrin metal–organic frameworks with phenolic resin
Houwei He, Zhongliao Wang, Jinfeng Zhang, Shavkat Mamatkulov, Olim Ruzimuradov, Kai Dai, Jingxiang Low, Yue Li
Abstract
A highly interface-adapted all-organic step-scheme photocatalyst based on porphyrin metal–organic frameworks and phenolic resin is constructed, which shows enhanced charge transfer dynamics and reduced O 2 activation energy barrier.
Topics & Concepts
Hydrogen peroxidePorphyrinRedoxKineticsChemistryMetal-organic frameworkMetalPhotochemistryInorganic chemistryOrganic chemistryQuantum mechanicsPhysicsAdsorptionPorphyrin and Phthalocyanine ChemistryAdvanced Nanomaterials in CatalysisMetal-Organic Frameworks: Synthesis and Applications