Effect of in-situ emulsification on CO2/N2-based cyclic solvent injection process for enhancing heavy oil recovery and CO2 storage
Jing Zhao, Yanfeng He, Jun Wang, Mingguo Peng, Jun Yang, Fanhua Zeng
Abstract
Surfactant-assisted CO 2 /N 2 -based CSI (SA CO 2 /N 2 -CSI) process emerges as a strategic solution to migrate the high energy consumption and carbon intensity associated with traditional thermal operations for heavy oil recovery. However, the interphase mass transfer makes the emulsification behavior in this process complex. In this study, the effect of in-situ emulsification on CO 2 /N 2 -CSI is assessed using a sandpack model and microchannel chip. Mesoscopically, SA CO 2 /N 2 -CSI outperforms conventional CO 2 /N 2 -CSI in terms of both oil recovery and CO 2 storage, owing to the enhanced CO 2 diffusion, oil solubilization, and foamy oil stability due to emulsification. Microscopically, the impact of emulsifier injection rate on oil removal efficiency in the dead-end pores becomes negligible when the injection rate exceeds 50 nL/min, providing insights to the emulsification mechanisms underlying the optimal pressure depletion rate (9 kPa/min) in SA CO 2 /N 2 -CSI. This study demonstrates the applicability of the SA CO 2 /N 2 -CSI in fostering sustainable heavy oil production and CO 2 storage.