Cobalt-catalyzed enantioselective [2+2+2] cycloaddition/electrocyclic ring opening cascade of aldehydes and diynes
Lefeng Lin, Lihan Zhu, B.G. Teng, Jiuli Xia, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
Topics & Concepts
CycloadditionCascadeChemistrySteric effectsEnantioselective synthesisCatalysisConjugated systemDensity functional theoryRing (chemistry)Computational chemistryCascade reactionCombinatorial chemistryBond cleavageStereochemistrySubstrate (aquarium)Cleavage (geology)DieneOrganic synthesisFunctional groupTriple bondPhotochemistrySingle bondAxial symmetryStereoselectivityTransition stateDouble bondCarbon fibersStereoisomerismMedicinal chemistryAxial and Atropisomeric Chirality SynthesisCatalytic Alkyne ReactionsAsymmetric Synthesis and Catalysis