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Design of Tannin-Based Poured Earth Material via Deflocculation–Coagulation Control: Additive Selection and Tannin Variation

Yi Du, Guillaume Habert, Coralie Brumaud

2022ACS Sustainable Chemistry & Engineering18 citationsDOI

Abstract

Combining the low environmental impact of vernacular earthen construction and the cost efficiency of the modern concrete pouring technique, poured earth is becoming more attractive for the construction sector nowadays. However, the development of poured earth is still in its infancy and few design options have been reported. In this study, we present a new type of poured earth based on natural tannin extracts and iron compounds. Tannin is used as a dispersant to liquefy clay materials, while the iron compound acts as an antitannin agent to slowly remove the dispersing effect and recoagulate clay. Specifically, iron compounds with different solubilities were selected and their complexation reaction kinetics with oak tannin were investigated through various techniques including UV–vis, ATR, XRD, and rheological measurements. Iron citrate was finally screened out because of its controlled speed of chelating tannin originating from various species with and without the presence of kaolinite. Such a study enables the production of a poured earth material based on natural additives with higher strength and water resistance. It paves the way for locally tailored solutions for circular and climate-neutral construction.

Topics & Concepts

TanninDispersantEarth (classical element)ChelationChemistryMaterials scienceChemical engineeringEnvironmental sciencePulp and paper industryMetallurgyMathematicsEngineeringFood sciencePhysicsOpticsDispersion (optics)Mathematical physicsRecycling and utilization of industrial and municipal waste in materials productionHygrothermal properties of building materialsInnovations in Concrete and Construction Materials
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