Synthesis and Thermal Reduction of Complexes [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3): Formation of Solid Solutions Ni3C1 –xВx
Еlena А. Malinina, Lyudmila V. Goeva, Г. А. Бузанов, В. М. Ретивов, Varvara V. Avdeeva, Nikolay T. Kuznetsov
Abstract
Abstract Nickel(II) complexes of the composition [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3) have been synthesized and studied. The thermal reduction of the complexes has been studied in the temperature range 20–800°C in air and in an inert atmosphere. Precursor complexes and their reduction products have been identified by elemental analysis, X-ray powder diffraction, and IR spectroscopy. The physicochemical study of the thermolysis product of complex [Ni(DMF)6][B10H10] shows that scarcely studied solid solutions of the composition Ni3C1 –xВx are formed.
Topics & Concepts
ChemistryInert gasThermal decompositionElemental analysisThermal analysisNickelPowder diffractionX-ray crystallographyInertAtmospheric temperature rangeInfrared spectroscopyNuclear chemistryCrystallographyInorganic chemistryDiffractionThermalOrganic chemistryMeteorologyOpticsPhysicsBoron Compounds in ChemistryRadioactive element chemistry and processingNuclear Materials and Properties