High-Responsivity Self-Powered Solar-Blind Photodetectors Based on Magnetron-Sputtered CuCrO₂/<i>β</i>-Ga₂O₃ p-n Heterojunction
Jialong Lin, Zifan Hong, M T Long, Shubo Wei, Xingkun Peng, Xiyao He, Hao Long, Jie Zhang, Weifeng Yang
Abstract
We report for the first time high-performance solar-blind self-powered photodetectors (PDs) based on magnetron-sputtered CuCrO2/ <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -Ga2O3 p-n heterojunction. Our CuCrO2/ <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -Ga2O3 PDs show a low dark current of 6.5 pA, a high responsivity of 50 mA/W, a high detectivity of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$3.7\times 10^{{12}}$ </tex-math></inline-formula> Jones, and a high external quantum efficiency (EQE) of 24.6%, which outperform most reported <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -Ga2O3-based heterojunction PDs. Such brilliant performances can be attributed to the high-quality CuCrO2 films enabled by in situ magnetron sputtering, which improve the photogenerated carrier mobility and collection efficiency. Furthermore, type-II band alignment between CuCrO2 and <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -Ga2O3 heterojunction is identified by X-ray photoelectron spectroscopy with the valence band offset of 2.61 eV and the conduction band offset of 0.87 eV, which facilitates the separation of photogenerated electrons and holes. These results show that the CuCrO2/ <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> -Ga2O3 heterojunction could achieve superior solar-blind sensitivity, thus indicating strong prospects in wide practical applications regarding solar-blind detection.