Photo-induced weak base-catalyzed synthesis of α-haloboronates from vinylboronates and polyfluoroalkyl halides
Tongchang Fang, Jian Qiu, Kai Yang, Qiuling Song
Abstract
An unprecedented strategy for the synthesis of sp<sup>2</sup>-<italic>α</italic>-haloboronates has been developed. Unique KOAc catalytic system, high synthetic application value of the product and no participation of metal constitute the notable features of this reaction.
Topics & Concepts
ChemistryHalideCatalysisBase (topology)MetalProduct (mathematics)Base metalCombinatorial chemistryOrganic chemistryMetallurgyGeometryMathematical analysisWeldingMaterials scienceMathematicsFluorine in Organic ChemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods