A Novel Functionalized Ionic Liquid for Highly Selective Extraction of TcO<sub>4</sub><sup>–</sup>
Yiwei Huang, Xiaomin Li, Fei Wu, Suliang Yang, Fangfei Dong, Xupeng Zhi, Xinlong Chen, Guoxin Tian, Yinglin Shen
Abstract
Due to the highly acidic and high-salinity nature of the high-level radioactive waste liquid (HLLW), selective extraction of TcO4– from HLLW remains to be a challenging task. Traditional anion exchangers show low selectivity and unsatisfactory extraction performance due to the lack of functional groups that can interact strongly with TcO4–. In this work, a tailor-made binding site was constructed by decorating two acetamide functional groups on imidazolium cation to fabricate a new Tc separation material, which exhibits high selectivity. Unlike most reported Tc separation materials, which can only perform well under low acidic, neutral, or alkaline conditions, this material still has good extraction performance in highly acidic solutions. In the simulated high-level waste liquid of 3 M nitric acid, the extraction efficiency of 0.5 mol/L organic phase for Tc can reach 96.5% through the first-stage extraction. Our theoretical simulations suggest that ReO4–/TcO4– anions were adsorbed on the top of the imidazolium ring during the extraction process, with p−π and p–p interactions acting as the driving forces.