Multifunctional Zn(<scp>ii</scp>)–Yb(<scp>iii</scp>) complex enantiomers showing second-harmonic generation, near-infrared luminescence, single-molecule magnet behaviour and proton conduction
Shui‐Dong Zhu, Jun‐Jie Hu, Lu Dong, He‐Rui Wen, Sui‐Jun Liu, Ying‐Bing Lu, Cai‐Ming Liu
Abstract
A new pair of Zn(<sc>ii</sc>)–Yb(<sc>iii</sc>) enantiomers with trinuclear structures were synthesized by using a chiral amine-phenol ligand, and they show unprecedented five-functionality by association of SMM, luminescent and proton conductive properties.
Topics & Concepts
LuminescenceMaterials scienceEnantiomerMoleculeProtonLigand (biochemistry)Thermal conductionAmine gas treatingInfraredCrystallographyOptoelectronicsStereochemistryReceptorOrganic chemistryChemistryOpticsPhysicsBiochemistryQuantum mechanicsComposite materialMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced NMR Techniques and Applications