Synthesis and near-infrared photothermal conversion of Cp*Rh-based [2]-catenanes in trapezoidal metallacycles
Pan‐Pan Hua, Huijun Feng, Xiang Gao, Li‐Fang Zhang, Guo‐Xin Jin
Abstract
Minor differences among pyridine ligands led to [2]-catenanes with dramatically different stacking modes of the building blocks, which facilitated the production of assemblies with different photothermal conversion abilities.
Topics & Concepts
CatenaneMetallacyclePhotothermal therapyStackingPyridineNear-infrared spectroscopyInfraredCyanMaterials scienceChemistryCrystallographyStereochemistryCombinatorial chemistryNanotechnologyOpticsPhysicsMoleculeOrganic chemistryDiffractionX-ray crystallographySupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryMolecular Sensors and Ion Detection