A smart sensing triazine hexacarboxylic metal–organic skeleton material: synthesis, structure and multifunctional fluorescence detector
Yao Xiao, Bing Li, Zi-Xin You, Yong Heng Xing, Feng Ying Bai, Lixian Sun, Zhan Shi
Abstract
A novel lanthanide metal organic framework [(NH<sub>2</sub>(Me)<sub>2</sub>)]<sub>6</sub>·[Tb<sub>3</sub>(TDPAT)<sub>2</sub>(μ<sub>2</sub>-O)<sub>1.5</sub>]·3EtOH·7.5H<sub>2</sub>O (complex <bold>1</bold>) was constructed <italic>via</italic> the reaction of 5,5′,5′′-(1,3,5-triazine-2,4,6-triyltriimino) tris(azanediyl)triisophthalate (H<sub>6</sub>TDPAT) and TbCl<sub>3</sub>·6H<sub>2</sub>O.
Topics & Concepts
Materials scienceLanthanideFluorescenceMetalTriazineCrystallographyPhysical chemistryPhysicsPolymer chemistryChemistryOrganic chemistryOpticsMetallurgyIonMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesCovalent Organic Framework Applications