A Comprehensive Review on Metal Organic Framework Based Preconcentration Strategies for Chromatographic Analysis of Organic Pollutants
Rajpal Verma, Gaurav Dhingra, Ashok Kumar Malik
Abstract
Organic pollutants (OPs) are of worldwide concern for being hazardous to human existence and natural flora and fauna in view of their contaminating nature, bio-aggregation properties and long range movement abilities in environment. Metal organic frameworks (MOFs) are a new kind of crystalline porous material, composed of metal ions and multi dentate organic ligands with well-defined co-ordination geometry exhibiting promising application respect to adsorptive evacuation of OPs for chromatographic analysis. Applications of MOFs as preconcentration material and column packing material are reviewed. Key analytical characteristics of MOF based preconcentration techniques and coupled chromatographic procedures are summarized in detail. MOF based preconcentration strategies are compared with conventional sorbent based extraction techniques for thorough evaluation of performance of MOF materials.