Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
Keli Wang, Hong‐Tao Ji, Qiong-Hui Peng, Jun Jiang, Li‐Juan Ou, Wei‐Min He
Abstract
With reusable sodium decatungstate (NaDT) as the photocatalyst, hydrocarbons (alkanes, ethers and ketones) as the alkylating agents, a wide range of alkylated fused N-heterocycles were obtained in high yield.
Topics & Concepts
AlkylationPhotocatalysisChemistryCascadeYield (engineering)Visible spectrumPhotochemistryOrganic chemistryCatalysisMaterials scienceOptoelectronicsChromatographyMetallurgyRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesPolyoxometalates: Synthesis and Applications