Advancing energy storage and supercapacitor applications through the development of Li+-doped MgTiO3 perovskite nano-ceramics
Hend S. Magar, A. M. Mansour, Ali B. Abou Hammad
Abstract
Abstract Perovskite oxide materials, specifically MgTiO 3 (MT) and Li-doped MgTiO 3 (MTxLi), were synthesized via a sol–gel method and calcination at 800 °C. This study explores the impact of varying Li doping levels (x = 0, 0.01, 0.05, and 0.1) on the crystalline structure and properties of MgTiO 3 . X-ray diffraction analysis revealed a well-defined rhombohedral MgTiO 3 phase. Optical diffuse reflectance measurements provided insights into energy gap values, refractive index, and dielectric constant. Li + doping enhanced the electrical properties of MgTiO 3 , with a notable phase transition observed at 50 °C. The study investigated impedance and AC conductivity under varying temperature and frequency conditions (25–120 °C, 4 Hz to 8 MHz). Electrochemical analysis through cyclic voltammetry and electrochemical impedance spectroscopy confirmed highly electrocatalytic properties for MTxLi, particularly when modified onto screen-printed electrodes. This work not only advances the understanding of Li-doped MgTiO 3 nanostructures but also highlights their significant potential for direct electrochemical applications, particularly in the realm of energy storage.