Iodine(<scp>i</scp>) complexes incorporating sterically bulky 2-substituted pyridines
Jas S. Ward, Rosa M. Gomila, Antonio Frontera, Kari Rissanen
Abstract
N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(i) and iodine(i) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions.
Topics & Concepts
Steric effectsIodineChemistryPyridineProtonationSolid-stateMedicinal chemistryStereochemistryOrganic chemistryPhysical chemistryIonCrystallography and molecular interactionsCrystal structures of chemical compoundsRadioactive element chemistry and processing