Acetone CoSolvent Reconstructs the Zn <sup>2+</sup> Solvation Sheath for Ultra‐Stable Zinc‐Ion Battery
Jinyu Zhang, Yang Liu, Xiaosheng Zhang, Lingyang Xue, Linlin Zhang, Xuying Liu
Abstract
The uncontrollable growth of zinc metal dendrites and the water‐induced parasitic reaction in pure aqueous electrolyte cause the poor cycling stability of zinc ion battery. Herein, a stable electrode/electrolyte interface with a dendrite‐free zinc anode is developed by adding acetone into the aqueous electrolyte. The as‐formed water/acetone hybrid solvent effectively optimizes the Zn 2+ solvation structure (coordinated water changes from 6 to 4) and induces the uniform zinc ion deposition through the high adsorption energy with the Zn (002) surface. It also stabilizes the zinc metal by reducing the corrosion reaction (hydrogen evolution) with water and the formation of a basic zinc salt by‐product. As a result, the symmetrical cell with the acetone/water electrolyte exhibits a superior stability of 3700 h (154 days) at 1 mA cm −2 . The battery with the Na 2 V 6 O 16 ·3H 2 O cathode delivers an 84.1% capacity retention after 1000 cycles at 1.0 A g −1 . The organic/aqueous electrolyte provides a new insight into understanding the relationship between solvation structure, electrode/electrolyte interface, and the performance of the zinc ion battery.