Enantioselective assembly and recognition of heterochiral porous organic cages deduced from binary chiral components
Chao Liu, Yucheng Jin, Dongdong Qi, Xu Ding, Huimin Ren, Hailong Wang, Jianzhuang Jiang
Abstract
. Interestingly, HPOC-1 exhibits circularly polarized luminescence and enantioselective recognition of chiral substrates according to the circular dichroism spectral change. Theoretical simulations have been carried out, rationalizing both the enantioselective assembly and recognition of HPOC-1.
Topics & Concepts
Enantioselective synthesisBinary numberPorosityPorous mediumChemistryNanotechnologyMaterials scienceOrganic chemistryCatalysisMathematicsArithmeticSupramolecular Chemistry and ComplexesMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Self-Assembly in Materials