Hydroxy and surface oxygen effects on 5-hydroxymethylfurfural oxidation to 2,5-furandicarboxylic acid on β-MnO<sub>2</sub>: DFT, microkinetic and experiment studies
Bunrat Tharat, Lappawat Ngamwongwan, Theerada Seehamongkol, Bunyarat Rungtaweevoranit, Jeeranan Nonkumwong, Suwit Suthirakun, Kajornsak Faungnawakij, Narong Chanlek, Aunyamanee Plucksacholatarn, Weerawan Nimsaila, Chanatkran Prommin, Anchalee Junkaew
Abstract
. Thus, considering both hydroxy and surface oxygen species is a new strategy for enhancing the catalytic activity of Mn oxides and other metal oxide catalysts for the HMF-to-FDCA reaction.
Topics & Concepts
CatalysisChemistryYield (engineering)OxygenManganeseSolventDimethyl sulfoxideMetalInorganic chemistryOrganic chemistryMaterials scienceMetallurgyCatalysis for Biomass ConversionCatalysis and Hydrodesulfurization StudiesNanomaterials for catalytic reactions