Regio- and stereoselective oxidative conversion of alkynes to sulfenylated α,β-unsaturated carbonyls
Meizhong Tang, Ye‐Xin Wang, Shenlin Huang, Lan‐Gui Xie
Abstract
An electrophilic sulfenylation promoted oxidation of alkynes is presented, providing the chemo-, regio- and stereoselective synthesis of α-sulfenylated α,β-unsaturated aldehydes.
Topics & Concepts
ChemistryStereoselectivityElectrophileRegioselectivityOxidative phosphorylationOrganic chemistryCombinatorial chemistryCatalysisBiochemistrySulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsChemical Synthesis and Reactions