First-principles calculations and device characterizations of formamidinium-cesium lead triiodide perovskite crystals stabilized by germanium or copper
Ayu Enomoto, Atsushi Suzuki, Takeo Oku, Sakiko Fukunishi, Tomoharu Tachikawa, Tomoya Hasegawa
Abstract
Abstract To avoid formation of the photo-inactive δ -phase of formamidinium-cesium lead triiodide, copper or germanium was added to the perovskite compounds to stabilize the photoactive α -phase. It was found that the substitution of lead by germanium (Ge) or copper (Cu) provided the stabilization of the α -phase in the present work. The first-principles molecular dynamics calculations indicated that displacements of formamidinium molecules were suppressed by the Ge doping. X-ray diffraction results indicated that the Ge or Cu doping of the perovskite compounds could be effective for suppression the phase transition from α - to δ -phase.
Topics & Concepts
FormamidiniumGermaniumPerovskite (structure)TriiodideCopperCaesiumDopingMaterials sciencePhase (matter)Inorganic chemistryChemistryCrystallographyPhysical chemistryOrganic chemistryOptoelectronicsSiliconMetallurgyElectrolyteDye-sensitized solar cellElectrodePerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyChalcogenide Semiconductor Thin Films