Reactivity of Stabilized Vinyldiazo Compounds toward Alkenyl- and Alkynylsilanes under Gold Catalysis: Regio- and Stereoselective Synthesis of Skipped Dienes and Enynes
Olaya Bernardo, Kota Yamamoto, Israel Fernández, Luís A. López
Abstract
) coupling. Mechanistic experiments and DFT studies have provided support for a stepwise mechanism.
Topics & Concepts
ChemistryStereoselectivityCatalysisReactivity (psychology)SilylationMedicinal chemistryOrganic chemistryCombinatorial chemistryAlternative medicineMedicinePathologyCyclopropane Reaction MechanismsCatalytic Alkyne ReactionsCatalytic C–H Functionalization Methods