Direct, stereoselective thioglycosylation enabled by an organophotoredox radical strategy
Peng Ji, Yueteng Zhang, Feng Gao, Fangchao Bi, Wei Wang
Abstract
Organophotoredox mediated HAT catalysis is developed for achieving high anomerically selective thioglycosylation of glycosyl bromides.
Topics & Concepts
StereoselectivityGlycosylCatalysisChemistryCombinatorial chemistryStereochemistryOrganic chemistryCarbohydrate Chemistry and SynthesisFluorine in Organic ChemistrySulfur-Based Synthesis Techniques