A strained intramolecular P/Al-FLP and its reactivity toward allene
Patrick Federmann, Tamino Bosse, Siad Wolff, Beatrice Cula, Christian Herwig, Christian Limberg
Abstract
An intramolecular P/Al-based FLP with a biphenylene scaffold is synthesized by a convenient Al-Sn exchange. Despite the spacer the FLP functions interact leading to a strained compound, capable of CO 2 binding and unprecedented allene activation.
Topics & Concepts
AlleneMoietyChemistryReactivity (psychology)LinkerIntramolecular forceBiphenyleneStereochemistryCombinatorial chemistryOrganic chemistryCatalysisOperating systemPathologyPolymerPhenyleneAlternative medicineComputer scienceMedicineOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and Catalysis