Litcius/Paper detail

Development of Heterocycle-Substituted and Fused Azulenes in the Last Decade (2010–2020)

Taku Shoji, Tetsuo Okujima, Shunji Ito

2020International Journal of Molecular Sciences48 citationsDOIOpen Access PDF

Abstract

Azulene derivatives with heterocyclic moieties in the molecule have been synthesized for applications in materials science by taking advantage of their unique properties. These derivatives have been prepared by various methods, involving electrophilic substitution, condensation, cyclization, and transition metal-catalyzed cross-coupling reactions. Herein, we present the development of the synthetic methods, reactivities, and physical properties for the heterocycle-substituted and heterocycle-fused azulenes reported in the last decade.

Topics & Concepts

AzuleneElectrophilic substitutionCombinatorial chemistryChemistryElectrophileMoleculeElectrophilic aromatic substitutionComputational chemistryOrganic chemistryCatalysisSynthesis and Properties of Aromatic CompoundsLuminescence and Fluorescent MaterialsPorphyrin and Phthalocyanine Chemistry