A Highly Stable Microporous Calcium-Based MOF for C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Separation with Low Regenerative Energy
Lulu Zhang, Feifan Lang, Xiao‐Juan Xi, Shunxian Yin, Jiandong Pang, Wenjun Zheng, Xian‐He Bu
Abstract
Most of the porous materials used for acetylene/carbon dioxide separation have the problems of poor stability and high energy requirements for regeneration, which significantly hinder their practical application in industries. Here, we report a novel calcium-based metal–organic framework (NKM-123) with excellent chemical stability against water, acids, and bases. Additionally, it has exceptional thermal stability, retaining its structural integrity at temperatures up to 300 °C. This material exhibits promising potential for separating C 2 H 2 and CO 2 gases. Furthermore, it demonstrates an adsorption heat of 29.3 kJ mol –1 for C 2 H 2, which is lower than that observed in the majority of MOFs used for C 2 H 2 /CO 2 separations. The preferential adsorption of C 2 H 2 over that of CO 2 is confirmed by dispersion-corrected density functional theory (DFT-D) calculations. In addition, the potential of industrial feasibility of NKM-123 for C 2 H 2 /CO 2 separation is confirmed by transient breakthrough tests. The robust cycle performance and structural stability of NKM-123 during multiple breakthrough tests show great potential in the industrial separation of light hydrocarbons.