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Photocatalytic reduction of Cr(VI) from aqueous solution by visible light/CuO-Kaolin: Optimization and modeling of key parameters using central composite design (CCD)

Azita Mohagheghian, Naghmeh Besharati-Givi, Kazem Godini, Raf Dewil, Mehdi Shirzad‐Siboni

2020Separation Science and Technology15 citationsDOI

Abstract

In the current research, a visible light photocatalytic method, in which the CuO/Kaolin nanocomposite photocatalyst was utilized to reduce Cr(VI), was investigated. Response surface methodology was applied to determine the influence of various variables (individual effect and correlated effects) and the optimum conditions for Cr(VI) reduction. Analysis of variance (ANOVA) indicated a high coefficient of determination value (R2 = 0.9812) for the developed second-order regression model, suggesting the suitability of the model. Approximately 99.99, 95.77 and 79.6% of Cr(VI) in a synthetic water, drinking water and electroplating wastewater samples were reduced, respectively.

Topics & Concepts

PhotocatalysisChemistryResponse surface methodologyCentral composite designAqueous solutionVisible spectrumNanocompositeElectroplatingComposite numberChemical engineeringWastewaterAnalytical Chemistry (journal)Nuclear chemistryEnvironmental engineeringComposite materialEnvironmental chemistryChromatographyCatalysisMaterials scienceOptoelectronicsPhysical chemistryOrganic chemistryLayer (electronics)EngineeringAdvanced Photocatalysis TechniquesTiO2 Photocatalysis and Solar CellsWater Quality Monitoring and Analysis